So i say these are ink, and they do look like ink but there actually food colouring / dye , but give the same effect.
This freebie has 17 different variations of coffee cup stains and splats Photoshop Brushes and the Original images
This is a collection of pages, covers, cardboard, and ripped up parts of old books
These textures were made using a high quality textured card, coffee granules and boiling water.
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24 various concrete textures some with cracks and stains availiable via flickr